From Chapter 1:
Every one knows the legend of the water (or beer) thrown over Sir Walter by his servant when he first saw his master smoking, and imagined he was on fire. The story was first associated with Raleigh by a writer in 1708 in a magazine called the British Apollo. According to this yarn Sir Walter usually "indulged himself in Smoaking secretly, two pipes a Day; at which time, he order'd a Simple Fellow, who waited, to bring him up a Tankard of old Ale and Nutmeg, always laying aside the Pipe, when he heard his servant coming." On this particular occasion, however, the pipe was not laid aside in time, and the "Simple Fellow," imagining his master was on fire, as he saw the smoke issuing from his mouth, promptly put the fire out by sousing him with the contents of the tankard. One difficulty about this story is the alleged secrecy of Raleigh's indulgence in tobacco. There seems to be no imaginable reason why he should not have smoked openly. Later versions turn the ale into water and otherwise vary the story.

From Chapter 8:
A famous crony of Parr's, the learned Porson, was another devotee of tobacco. In November 1789 Parr wrote to Dr. Burney: "The books may be consulted, and Porson shall do it, and he will do it. I know his price when he bargains with me; two bottles instead of one, six pipes instead of two, burgundy instead of claret, liberty to sit till five in the morning instead of sneaking into bed at one: these are his terms:" and these few lines, it may be added, give a graphic picture of Porson. According to Maltby, Porson once remarked that when smoking began to go out of fashion, learning began to go out of fashion also—which shows what nonsense a learned man could talk.